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Fabrication and structural analysis of Al, Ga, and In nanocluster crystals

by: Jin-Feng Jia, Xi Liu, Jun-Zhong Wang, Jian-Long Li, XS Wang, Qi-Kun Xue, Zhi-Qiang Li, Zhenyu Zhang, SB Zhang
Physical Review B, Vol. 66, No. 16. (23 October 2002), 165412.


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Artificial nanocluster crystals of In; Ga; and Al were fabricated using a technique in which surface mediated magic clustering is used to achieve identical cluster size while the Si(111)-7Ã7 surface is used as a template for ordering the clusters. The atomic structures; formation mechanism and stability of the nanoclusters were studied with in situ scanning tunneling microscopy combined with first-principles total energy calculations. Our study shows that delicate control of growth kinetics is extremely important for cluster crystal fabrication; and there is essentially no limitation to this method. The high thermal stability and unique structure make these artificial nanocluster crystals promising for various applications.


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